I have tried that particular dot, but have done other MRDS sights on revolvers. I actually have better luck training my sight picture by placing the front sight in the dot window, and rolling the muzzle down, to find the dot. This is assuming you have only the front sight, and not the rear irons.
Whether this works, or Rod's method, it will take a fair amount of practice. The nice thing is that it does not cost ammunition to practice this. And once you have it down, you are probably really going to like the red dot.
Craig